HOW TO PREPARE POTASH ALUM?
OBJECT :
To prepare potash alum (K2SO4,Al2(SO4)3.24H2O)
APPARATUS :
China dish,beaker,watch glass,funnel,conical flask,glass rod,filter paper,water trough,wire gauze,tripod stand and bunsen burner.
CHEMICALS :
Solid Aluminium sulphate [Al2(SO4)3.16H2O](7.7 gms) , K2SO4 (2.0 gms), 50 mls of distilled water,few drops of conc H2SO4
EQUATIONS :
K2SO4 +Al2 (SO4)3.16H2O + 8H2O --------------> K2SO4.Al2(SO4)3.24H2O
THEORY :
The term alum was originally used for potassium aluminium sulphate [K2SO4.Al2(SO4)3.24H2O] commonly known as potash alum.The term alum is now used for all double sulphates having general formula R2SO4.M2(SO4)3.24H2O
PROCEDURE :
Weigh out 7.7 gm of aluminium sulphate and dissolve it in about 30 mls of boiling distilled water.Add few drops of H2SO4 (conc) to make the solution clear.In another beaker dissolve 2.0 g of K2SO4 in 20 mls of distilled water.Mix the two solutions and concentrate the solution to crystallization by heating it in a china dish.Now cool this concentrated solution in ice cold water.After few minutes, crystals of alum separates out.
RESULT :
Colorless crystals of potash alum are obtained.
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